Just follow the simple steps-


To create a new shortcut for Google Talk:

1)Right-click on the desktop or anywhere you want to place the GTalk shortcut.
2)Select New on the right click context menu.
3)Then select Shortcut.
4)Copy and paste the following line to the text box when prompted to type the location of the item:
“c:\program files\google\google talk\googletalk.exe” /nomutex

5)Click on Next.
6)Give the shortcut a proper name such as Google Talk or Google
Talk Multiple or Google Talk Polygamy.
8)Click OK until you are done.